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This work proves the feasibility of utilizing steady state and transient in situ/operando spectroscopy to extract mechanistic information that reduces and leads to robust kinetic models. It also opens new avenues to explore kinetics and mechanisms with charge transfer data in heterogeneous catalysis.more » « lessFree, publicly-accessible full text available June 13, 2026
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Torres-Velasco, A; Patil, B; Srinivasan, P; Zhu, H; Qi, Y; Podkolzin, S G; Bravo-Suarez, J J (, https://www.icc-lyon2024.fr/en/scientific-program/detailed-program/47)The development of simple in situ spectrokinetic techniques to assess intermediate species nature and adsorption location can benefit catalytic studies by providing insights into the reasons for different catalysts performance and facilitate mechanistic proposals.more » « less
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